|
Preface |
6 |
|
|
About the Book |
8 |
|
|
Contents |
9 |
|
|
Acronyms and Nomenclature |
12 |
|
|
Introduction |
14 |
|
|
References |
15 |
|
|
1 Structure and Properties of Liquid-Crystal Nanomaterials |
16 |
|
|
1.1 Classification and Structure of Liquid-Crystal Nanomaterials |
17 |
|
|
1.2 Mesomorphous and Optical Properties of Cholesteric Liquid-Crystal Nanomaterials |
22 |
|
|
1.3 Physical Anisotropy and Application of Cholesteric Liquid-Crystal Nanomaterials |
31 |
|
|
References |
34 |
|
|
2 Tribology and Lubrication of Solids |
36 |
|
|
2.1 Modern Antifriction and Antiwear Additives in Tribology (Passive Friction Control) |
37 |
|
|
2.2 Present-Day Advances in Control of Antifriction Behavior of Solids (Active Friction Control) |
57 |
|
|
2.3 Effect of Lattice-Ordered Lubricant Film on Friction of Solids |
65 |
|
|
2.3.1 Structure of Fine Fluid Layers on the Solid Body Contact |
66 |
|
|
2.3.2 Surface Forces in Fine Fluid Interlayers |
72 |
|
|
2.3.3 Effects Observed During Deformation of Structured Boundary Layers |
76 |
|
|
2.3.4 The Concept of the Micropolar Fluid and Related Hydrodynamic Effects |
86 |
|
|
2.4 Tribology of Synovial Joints—Unique Natural Rubbing Organs |
91 |
|
|
2.4.1 Theories and Hypotheses About Lubrication in the Living Joints |
91 |
|
|
2.4.2 Conceptual Approaches to the Explanation of Low Friction in the Joints |
98 |
|
|
References |
106 |
|
|
3 Engineering and Technique of Experimental Tests of Liquid-Crystal Nanomaterials |
115 |
|
|
3.1 Triboengineering Tests |
115 |
|
|
3.1.1 Triboengineering Tests on Standard Equipment |
115 |
|
|
3.1.2 Integral-Counting Method for Estimation of Small Variations of Oscillation Parameters for High-Precision Tribometry |
117 |
|
|
3.1.3 Experimental Setup for the Simulation of Friction Processes in Natural Rubbing Organs–Joints |
127 |
|
|
3.1.4 Tribometric Equipment for Precision Tests of Metal- and Biopolymer Coupling |
132 |
|
|
3.2 Methods to Determine the Structuring Additives and Their Content in the Basic Compositions |
149 |
|
|
3.2.1 Infrared Spectroscopy |
149 |
|
|
3.2.2 Determination of the Concentration of the Liquid Crystal Additive in the Base Compositions by Measuring a Rotation Angle of Polarization Plane |
150 |
|
|
3.2.3 Development of Methods and Equipment to Control the Mesophase of Cholesteric Liquid-Crystal Nanomaterials and Their Compounds |
151 |
|
|
References |
153 |
|
|
4 Tribological Properties of Liquid-Crystal Nanomaterials |
156 |
|
|
4.1 Influence of Liquid-Crystal Nanomaterials on Friction of Chemically-Inactive Materials |
156 |
|
|
4.2 Influence of Liquid-Crystal Nanomaterials on Friction of Metal Tribosystems |
160 |
|
|
4.3 Adsorptive Properties of Liquid-Crystal Compounds |
172 |
|
|
4.3.1 Interaction of Liquid-Crystal Nanomaterials with Hard Surface in Static Contact |
173 |
|
|
4.3.2 Triboinduced Adsorption of Liquid-Crystal Nanomaterials Under Frictional Interaction of Solids |
177 |
|
|
4.4 The Role of Liquid-Crystal Additives in Mechanism of Friction, Wear, and Lubrication of Tribosystems |
182 |
|
|
4.5 Diagnostics of Liquid-Crystal Cholesterol Compounds in Lubricants by Optical Methods |
187 |
|
|
4.6 Lubricity of Cholesteric Liquid-Crystal Nanomaterials and Their Mixtures Depending on Temperature |
191 |
|
|
References |
196 |
|
|
5 Practical Application of Liquid-Crystal Nanomaterial in Engineering and Medicine |
200 |
|
|
5.1 Application of Liquid-Crystal Nanomaterials When Running-In of Internal-Combustion Engines |
200 |
|
|
5.2 Liquid-Crystal Nanomaterials as Antiwear Engine Oil Additives |
205 |
|
|
5.3 Assessment of Liquid-Crystal Compositions’ Efficiency When Polishing of Diamonds |
208 |
|
|
5.4 Artificial Mediums Based on Liquid-Crystal Nanomaterials for Correction of Joint Tribology |
210 |
|
|
5.5 Lubricants Based on Vacuum Oil Distillates and Liquid-Crystal Nanomaterials |
214 |
|
|
References |
219 |
|
|
Conclusions |
221 |
|
|
Index |
223 |
|